We report a facile halide ion (Cl(-) or Br(-)) mediated synthesis of Fe nanoparticles (NPs) by thermal decomposition of Fe(CO)5. The NP structure is controlled to be either amorphous (in the absence of halide ions) or single crystalline bcc (in the presence of halide ions). Through systematic investigation on the synthetic conditions, we have confi...


CO oxidation is an important reaction both experimentally and industrially, and its performance is usually dominated by the surface charge state. For example, CO oxidation on platinum (Pt) surface requires a proper charge state for the balance of adsorption and activation of CO and O2. Here, we present a “Mott−Schottky modulated catalysis” on Pt na...
It’s not hard to see why governments would seek to defend their languages. But some linguists think a staunch anti-English stance may be counterproductive. Truly endangered languages tend to be encroached on mostly by their dominant geographic neighbors, says Selma Sonntag, a political scientist at Humboldt State University who studies language purist movements: “The threat isn’t from English, it’s from whatever the official language is within their area.” Linguist David Crystal, author of “English as a Global Language,” has written about how Welsh-language purism may be furthering an elitism that prevents younger speakers from adopting the tongue. And it’s worth noting that English owes much of its vitality to its long history of borrowing from French, Latin, Arabic, and pretty much any other language it met. “Loanwords...do alter [a language’s] character—but is this a bad thing?” Crystal told me. “Imagine English without French or Latin loanwords. No Shakespeare, for a start.”
Several weeks prior to the announcement of the investigation, Ling continued to make appearances on state television in his positions of CPPCC Vice Chairman and United Front chief. On December 15 Ling had penned an article on the Communist theory publication Qiushi brimming with praise for the signature political philosophies of Xi Jinping such as the "Chinese Dream". This was seen by observers as a 'last-ditch' declaration of fealty to the new Chinese leader with whom Ling was thought to have lost favour.[11]
A kind of Ti–Fe–Ni–C compound powder was prepared by a novel precursor pyrolysis process using ferro-titanium, carbonyl nickel powder and sucrose as raw materials. The powder had a very compact structure and was uniform in particle size. The TiC–Fe36Ni composite coatings were simultaneously in-situ synthesized by Reactive Detonation-gun Spraying (RDS) using these Ti-Fe-Ni-C compound powders. The coatings presented typical morphology of thermal spraying coatings with two different areas: one was the area of TiC distribution where the round fine TiC particles (from 300nm to 1μm) were dispersed in the Fe36Ni alloy matrix; the other was the area of TiC accumulation (from 2 to 4μm). The surface hardness of the composite coating reached about 94 ± 2(HR15N).
The importance of porous carbon as the support material is well recognized in the catalysis community, and it would be even more attractive if several characteristics are considered, such as the stability in acidic and basic media or the ease of noble metal recovery through complete burn off. Because it is still difficult to obtain constant propert...
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