Pt alloy nanowires (NWs) were synthesized and applied as catalysts in the title reaction. The specific activity and mass activity of 2.5 nm wide FePt NWs were higher than of a commercial Pt catalyst. The stability of FePt NWs was tested by scanning the potential in an O(2) -saturated HClO(4) solution. The corresponding polarization curves before an...
We report a facile halide ion (Cl(-) or Br(-)) mediated synthesis of Fe nanoparticles (NPs) by thermal decomposition of Fe(CO)5. The NP structure is controlled to be either amorphous (in the absence of halide ions) or single crystalline bcc (in the presence of halide ions). Through systematic investigation on the synthetic conditions, we have confi...
Monodisperse cobalt (Co) nanoparticles (NPs) were synthesized and stabilized against oxidation via reductive annealing at 600C. The stable Co NPs are active for catalyzing the oxygen evolution reaction (OER) in 0.1 M KOH, producing a current density of 10 mA/cm2 at an overpotential of 0.39 V (1.62 V vs. RHE, no iR-correction). Their catalysis is s...
In this communication, we report a facile approach to constructing catalytic active hierarchical interfaces in 1-dimensional (1D) nanostructure, exemplified by the synthesis of TiO2-supported PtFe-FeOx nanowires (NWs). The hierarchical interface, constituting of atomic level interactions between PtFe and FeOx within each NW and the interactions bet...
But that imbalance can build resentment. In France, the secretary of the Academie Française called last December for a “reconquest of the French language” from loanwords; in China, government-friendly papers printed screeds this spring against “Wi-Fi,” “VIP,” and “e-mail.” Even as many governments work to protect languages from the spread of English, however, speakers in those countries go blithely off to “hot jooga,” meaning that official policy and the daily reality of English may be very different things.
Taming interfacial electronic effects on Pt nanoparticles modulated by their concomitants has emerged as an intriguing approach to optimize Pt catalytic performance. Here, we report Pt nanoparticles assembled on vacancy-abundant hexagonal boron nitride nanosheets and their use as a model catalyst to embrace an interfacial electronic effect on Pt in...
When languages are full of borrowed words, it’s often not by choice. Romany has many loans because of a history of extreme marginalization. Japan has a long tradition of cultural borrowing; it was also occupied for years after World War II. Vietnam, following centuries of successive occupations, has a high rate of Chinese and French loans presaging more recent English ones like “canguru,” according to the Max Planck research. Other languages are more deliberately open: According to research by Anne-Line Graedler, an English professor at Norway’s Hedmark University College, the Danes are the most welcoming Scandinavian country to loans.
Sub-10 nm nanoparticles (NPs) of M(II)-substituted magnetite MxFe3-xO4 (MxFe1-xO•Fe2O3) (M = Mn, Fe, Co, Cu) were synthesized and studied as electrocatalysts for oxygen reduction reaction (ORR) in 0.1 M KOH solution. Loaded on commercial carbon support, these MxFe3-xO4 NPs showed the M(II)-dependent ORR catalytic activities with MnxFe3-xO4 being th...
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