Controlling the physical and chemical properties of alloy nanoparticles (NPs) is an important approach to optimize NP catalysis. Unlike other tuning knobs, such as size, shape and composition, crystal structure has received limited attention and not been well understood for its role in catalysis. This deficiency is mainly due to the difficulty in s...

Pt alloy nanowires (NWs) were synthesized and applied as catalysts in the title reaction. The specific activity and mass activity of 2.5 nm wide FePt NWs were higher than of a commercial Pt catalyst. The stability of FePt NWs was tested by scanning the potential in an O(2) -saturated HClO(4) solution. The corresponding polarization curves before an...


Taming interfacial electronic effects on Pt nanoparticles modulated by their concomitants has emerged as an intriguing approach to optimize Pt catalytic performance. Here, we report Pt nanoparticles assembled on vacancy-abundant hexagonal boron nitride nanosheets and their use as a model catalyst to embrace an interfacial electronic effect on Pt in...
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