Highly active, low-cost, and durable electrocatalysts for the water oxidation reaction are pivotal in energy conversion and storage schemes. Here we report the nitride-core, oxide-shell-armor structured FeCoNi oxynitride as an efficient oxygen evolution electrocatalyst with a homogeneously nitride (Fe0.70Co0.56Ni0.92N1.0O0.06) core and oxide (Fe0.4...


Sometimes purism peaks after a war or in a post-colonial situation. South Korea tried to de-Japanify its language after World War II; the Indian and Pakistani governments tried to separate Hindi and Urdu after their partition. A purist approach can also be a smaller language’s way of resisting outside influence. In Iceland, the Icelandic Language Institute preserves the country’s Viking-era language by cobbling together new terms from indigenous roots. Some Native American groups do the same to resist English.
It’s not hard to see why governments would seek to defend their languages. But some linguists think a staunch anti-English stance may be counterproductive. Truly endangered languages tend to be encroached on mostly by their dominant geographic neighbors, says Selma Sonntag, a political scientist at Humboldt State University who studies language purist movements: “The threat isn’t from English, it’s from whatever the official language is within their area.” Linguist David Crystal, author of “English as a Global Language,” has written about how Welsh-language purism may be furthering an elitism that prevents younger speakers from adopting the tongue. And it’s worth noting that English owes much of its vitality to its long history of borrowing from French, Latin, Arabic, and pretty much any other language it met. “Loanwords...do alter [a language’s] character—but is this a bad thing?” Crystal told me. “Imagine English without French or Latin loanwords. No Shakespeare, for a start.”
Using FePtAu nanoparticles (NPs) as an example, this Communication demonstrates a new structure-control strategy to tune and optimize NP catalysis. The presence of Au in FePtAu facilitates FePt structure transformation from chemically disordered face-centered cubic (fcc) structure to chemically ordered face-centered tetragonal (fct) structure, and...
Monodisperse cobalt (Co) nanoparticles (NPs) were synthesized and stabilized against oxidation via reductive annealing at 600C. The stable Co NPs are active for catalyzing the oxygen evolution reaction (OER) in 0.1 M KOH, producing a current density of 10 mA/cm2 at an overpotential of 0.39 V (1.62 V vs. RHE, no iR-correction). Their catalysis is s...
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