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Pt alloy nanowires (NWs) were synthesized and applied as catalysts in the title reaction. The specific activity and mass activity of 2.5 nm wide FePt NWs were higher than of a commercial Pt catalyst. The stability of FePt NWs was tested by scanning the potential in an O(2) -saturated HClO(4) solution. The corresponding polarization curves before an...
A kind of Ti–Fe–Ni–C compound powder was prepared by a novel precursor pyrolysis process using ferro-titanium, carbonyl nickel powder and sucrose as raw materials. The powder had a very compact structure and was uniform in particle size. The TiC–Fe36Ni composite coatings were simultaneously in-situ synthesized by Reactive Detonation-gun Spraying (RDS) using these Ti-Fe-Ni-C compound powders. The coatings presented typical morphology of thermal spraying coatings with two different areas: one was the area of TiC distribution where the round fine TiC particles (from 300nm to 1μm) were dispersed in the Fe36Ni alloy matrix; the other was the area of TiC accumulation (from 2 to 4μm). The surface hardness of the composite coating reached about 94 ± 2(HR15N).
Lanthanum-transition-metal perovskites with robust meso-scale porous frameworks (meso-LaMO3) are synthesized through the use of ionic liquids. The resultant samples demonstrate a rather high activity for CO oxidation, by taking advantage of unique nanostructure-derived benefits. This synthesis strategy opens up a new opportunity for preparing functional mesoporous complex oxides of various compositions.
SHANDONG, East China — The unmistakable wail of the suona pierces the dusk in the village as Wang Ruiyong plays a traditional tune on the double-reed instrument. The elderly funeral attendees approve, recognizing the melody. Yet for nearly five years now, Wang and other suona masters have been recording their repertoire in the fear that the songs could soon be forgotten as their tradition increasingly comes under threat.
Sub-10 nm nanoparticles (NPs) of M(II)-substituted magnetite MxFe3-xO4 (MxFe1-xO•Fe2O3) (M = Mn, Fe, Co, Cu) were synthesized and studied as electrocatalysts for oxygen reduction reaction (ORR) in 0.1 M KOH solution. Loaded on commercial carbon support, these MxFe3-xO4 NPs showed the M(II)-dependent ORR catalytic activities with MnxFe3-xO4 being th...